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Especially now, as the Four High (High feed, High matte grade, High oxygen concentration, High volumetric heat capacity) technology  has being used to improve the single production ability of the flash smelting furnace, the furnace heat load has being increased correspondingly, and thus, the flash smelting furnace, especially the inner wall of reaction shaft, will be damaged more rapid [6,7]. Therefore, how to protect the reaction shaft is the main problem to be solved for intensified flash smelting process.
In this paper, Chou model was modified according to the practical situation in metal oxidation, then the reaction between metal and gas was described by the modified Chou model and parabolic rate law for comparison. Furthermore, the addition of Mg in the copper and aluminum alloys was investigated by calculating the experimental data chosen from literatures. Kinetics model for oxidation of metals and alloys The parabolic rate law  is used extensively in metal oxidation which was developed under the assuming that cationic transport across the growing oxide layer controls the rate of scaling.
Mei, K. F. Li, J. H. L. Ge: Trans Nonferrous Met Soc China, Vol. 631.  M. Nakamoto, A. Kiyose, T. Tanaka, L. Holappa and M. Hämäläinen: The Iron and Steel Institute of Japan, Vol. 38.  M. Nakamoto, T. Tanaka, L. Holappa and M. Hämäläinen: The Iron and Steel Institute of Japan, Vol. 211.  M. Nakamoto, M. Hanao, T. Tanaka, M. Kawamoto, L. Holappa and M. Hämäläinen: The Iron and Steel Institute of Japan, Vol. 1075.  M. Hanao, T. Tanaka, M. Kawamoto and K. Takatani: The Iron and Steel Institute of Japan, Vol.